てっきり
I was sure (but I was wrong)
てっきり + 〜と思っていた / 〜と思った
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てっきり means "I was convinced that…", and it almost always comes before a mistaken belief: てっきり晴れると思っていたのに、雨だった, "I was sure it would be sunny, but it rained".
The ending is nearly always と思っていた or と思った, followed by the reality that proved you wrong. Often のに, が or けど introduce the correction, or it's simply left unsaid.
That's the key difference from きっと. きっと is a confident guess about something that hasn't happened yet: 明日はきっと晴れる. てっきり looks back at a belief that turned out false.
It's a conversational word, perfect for describing surprises and misunderstandings.
Examples
てっきり晴れると思っていたのに、雨だった。
I was sure it would be sunny, but it rained.
てっきり彼が犯人だと思っていた。
I was convinced he was the culprit.
てっきり休みだと思っていたら、店は開いていた。
I was sure it was closed, but the shop was open.
静かだったので、てっきり誰もいないと思った。
It was so quiet I assumed no one was there.
てっきり怒られると思ったが、褒められた。
I was sure I'd be told off, but I was praised.